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coal combustion flue gas is widely accepted as the most developed and commercially viable method. Application of sorbent injection in coal-fired utility boilers is very challenging because of lower concentrations of mercury and the range of mercury forms in coal combustion flue gases.

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Coal fired boilers normally operate with 3-3.5% O2 (about 20% excess air). Whereas natural gas boilers normally operate at 1-1.5% O2 (about 7% excess air).? Steam and exit gas temperatures. Upon switching from coal to natural gas, heat transfer characteristics of a boiler will be impacted.

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As a safety factor to assure complete combustion, boilers are fired with excess air. One of the factors influencing NOx formation in a boiler is the excess air levels. High excess air levels (>45%) may result in increased NOx formation because the excess nitrogen and oxygen in the combustion air entering the flame will combine to form thermal NOx.

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In addition to almost any coal, many byprod- ucts and waste fuels (e.g., coke breeze, wood wastes, wood bark, and bagasse) can be burned successfully in stoker-fired boilers. However, pulverized coal-fired boilers can change load more rapidly. Figure 1 shows a simplified cross section of a typical industrial, na- tural-circulation boiler.

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